WEICONLOCK SUPERLIM 12GR

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Sikkerhetsinformasjon.

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed 19.06.2015 revision 18.06.2015 (GB) Version 8.4 Contact VA 100 WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 1/9 ! SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Name of product Contact VA 100 Code-Nr. 120500 1.2. Relevant identified uses of the substance or mixture and uses advised against ! Recommended intended purpose(s) 1-Component Cyanacrylat - Adhesives 1.3. Details of the supplier of the safety data sheet Distributor WEICON GmbH & Co. KG Königsberger Straße 255, DE-48157 Münster Postbox 84 60, DE-48045 Münster Phone ++49(0)251 / 9322 - 0, Fax ++49(0)251 / 9322 - 244 E-Mail : [email protected] Internet www.weicon.de Advice Produktsicherheit / Product-Safety-Department Phone ++49(0)251 / 9322 - 0 E-mail (competent person): [email protected] 1.4. Emergency telephone number Emergency advice GIZ Bonn (German, English) Phone ++49(0)228-19 240 Manufacturer WEICON GmbH & Co. KG Königsberger Str. 255, DE-48157 Münster Postbox 84 60, DE-48045 Münster 1.4. Emergency telephone number Emergency advice - Phone - SECTION 2: Hazards identification 2.1. Classification of the substance or mixture  Classification according to Regulation (EC) No 1272/2008 [CLP/GHS] Hazard classes and Hazard categories Hazard Statements Classification procedure Skin Irrit. 2 H315 Eye Irrit. 2 H319 STOT SE 3 H335 Hazard Statements H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. 2.2. Label elements Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed 19.06.2015 revision 18.06.2015 (GB) Version 8.4 Contact VA 100 WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 2/9 Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS] GHS07 Signal word Warning Hazard Statements H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Precautionary Statements P102 Keep out of reach of children. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P332 + P313 If skin irritation occurs: Get medical advice/attention. P337 + P313 If eye irritation persists: Get medical advice/attention. P362 Take off contaminated clothing. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container to hazardous or special waste collection point. Special rules for supplemental label elements for certain mixtures Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. 2.3. Other hazards Results of PBT and vPvB assessment The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII. SECTION 3: Composition/ information on ingredients Description One-component adhesive based on cyanoacrylate acid alkyl ester. 3.2. Mixtures Hazardous ingredients CAS No EC No Name [% weight] Classification according to Regulation (EC) No 1272/2008 [CLP/GHS] 7085-85-0 230-391-5 ethyl 2-cyanoacrylate 80 - 99,9 Eye Irrit. 2, H319 / STOT SE 3, H335 / Skin Irrit.  2, H315 not applicable Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed 19.06.2015 revision 18.06.2015 (GB) Version 8.4 Contact VA 100 WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 3/9 ! SECTION 4: First aid measures 4.1. Description of first aid measures General information Remove contaminated soaked clothing immediately. Take affected person into fresh air. In case of inhalation Remove the casualty into fresh air and keep him immobile. In the event of symptoms refer for medical treatment. In case of skin contact In case of contact with skin wash off immediately with soap and water. Do not take off solidified product from skin. Refer for medical treatment. ! In case of eye contact After eye contact, rinse opened eye for 15 minutes under running water. Transfer to hospital for specialist examination. In case of ingestion Call for a doctor immediately. 4.2. Most important symptoms and effects, both acute and delayed Physician's information / possible symptoms Coughing Shortness of breath Respiratory complaints skin irritation 4.3. Indication of any immediate medical attention and special treatment needed No information available. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Alcohol-resistant foam Dry powder Carbon dioxide Unsuitable extinguishing media Full water jet 5.2. Special hazards arising from the substance or mixture In case of fire formation of dangerous gases possible. Nitrogen oxides (NOx) Carbon monoxide (CO) Carbon dioxide (CO2) 5.3. Advice for firefighters Special protective equipment for fire-fighters Fire-fighting operations, rescue and clearing work under effect of combustion and smoulder gases just may be done with breathing apparatus. Do not inhale explosion and/or combustion gases. Additional information Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations. Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed 19.06.2015 revision 18.06.2015 (GB) Version 8.4 Contact VA 100 WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 4/9 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Ensure adequate ventilation. Use personal protective clothing. Use breathing apparatus if exposed to vapours/dust/aerosol. 6.2. Environmental precautions Do not discharge into the drains or bodies of water.. 6.3. Methods and material for containment and cleaning up Take up with absorbent material (e.g. sand, kieselguhr, acid binder, general-purpose binder, sawdust). Disposal according to regulations. 6.4. Reference to other sections Safe handling: see section 7 Disposal: see section 13 Personal protection equipment: see section 8 SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Care for thoroughly room ventilation, if necessary use in well ventilated area with local exhaust ventilation at workplace. Open and handle container with care! General protective measures Avoid contact with eyes and skin Do not inhale gases/vapours/aerosols. Hygiene measures At work do not eat, drink and smoke. Wash soiled clothing immediately. Wash hands before breaks and after work. Advice on protection against fire and explosion Pay attention to general rules of internal fire prevention. 7.2. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep in closed original container. Advice on storage compatibility Do not store together with animal feedstuffs. Do not store together with food. Keep away from water. Further information on storage conditions Keep container tightly closed and store at cool and aired place. Protect from heat and direct solar radiation. 7.3. Specific end use(s) Recommendation(s) for intended use See section 1.2 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed 19.06.2015 revision 18.06.2015 (GB) Version 8.4 Contact VA 100 WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 5/9 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Ingredients with occupational exposure limits to be monitored CAS No Name Code [mg/m3] [ppm] Remark 7085-85-0 Ethyl cyanoacrylate 8 hours Short-term 1.5 0.3 EH40/2005 Additional advice The statutory local and national regulations have to be observed. 8.2. Exposure controls Respiratory protection In case of insufficient ventilation or long-term effect use breathing apparatus. Hand protection In the cases of special applications, it is recommended to check the chemical resistance with the manufacturer of the gloves. In the cases of special applications, it is recommended to check the chemical resistance with the manufacturer of the gloves. Glove material specification [make/type, thickness, permeation time/life, wetting resistance]:: Nitrile rubber; 0,4mm; 480min;60min. Eye protection tightly fitting goggles Other protection measures protective clothing Appropriate engineering controls Sufficient ventilation and exhaustion. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance liquid Colour colourless Odour typical, pungent Odour threshold not determined Important health, safety and environmental information Value Temperature at Method Remark pH value not determined boiling point 214 °C 1003 mbar melting point -31 °C Flash point 82,5 °C Vapourisation rate not determined Flammable (solid) not determined Flammability (gas) not determined Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed 19.06.2015 revision 18.06.2015 (GB) Version 8.4 Contact VA 100 WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 6/9 Value Temperature at Method Remark Ignition temperature not determined Self ignition temperature 480 °C Lower explosion limit not applicable Upper explosion limit not applicable Vapour pressure < 21 Pa Relative density 1,043 g/cm3 20 °C Vapour density not determined Solubility in water Reacts with water Solubility/other 91,8 mg/l acetone Partition coefficient noctanol/water (log P O/W) 0,776 Decomposition temperature not determined Viscosity 2,6 mPa*s 20 °C Oxidising properties no Explosive properties not applicable 9.2. Other information No information available. SECTION 10: Stability and reactivity 10.1. Reactivity No information available. 10.2. Chemical stability No information available. 10.3. Possibility of hazardous reactions Reactions with oxidising agents. Explosive reaction with water Reactions with alcohols, amines, aqueous acids and alkalies. 10.4. Conditions to avoid After contact with water: Keep away from heat. Risk of polymerisation. 10.5. Incompatible materials Materials to avoid Alkali (lye) Alcohols Amines Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed 19.06.2015 revision 18.06.2015 (GB) Version 8.4 Contact VA 100 WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 7/9 Oxidising agent, strong Water 10.6. Hazardous decomposition products Gases/vapours, toxic Carbon monoxide and carbon dioxide. Nitrous oxides (NOx) Thermal decomposition Remark No decomposition if used as directed. Additional information Polymerization under development of heat. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity/Irritability/Sensitization Value/Validation Species Method Remark LD50 acute oral > 5000 mg/kg rat OECD 401 LD50 acute dermal > 2000 mg/kg rabbit OECD 402 Irritability skin irritant Irritability eye irritant Skin sensitization non-sensitizing Subacute Toxicity - Carcinogenicity Value Species Method Validation Chronic Toxicity - Mutagenicity No experimental information on genotoxicity in vitro available. ReproductionToxicity No indications of toxic effects were observed in reproduction studies in animals. Carcinogenicity No indications of carcinogenic effects are available from long-term trials. Specific target organ toxicity (single exposure) not applicable Specific target organ toxicity (repeated exposure) not applicable Aspiration hazard not determined Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed 19.06.2015 revision 18.06.2015 (GB) Version 8.4 Contact VA 100 WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 8/9 Experiences made from practice Persons suffering from hypersensitivity showed sensitization. Irritates mucous membranes. Irritates eyes and skin. Additional information The product is to be handled with the caution usual with chemicals. Other hazardous properties may not be excluded. SECTION 12: Ecological information 12.1. Toxicity No information available. 12.2. Persistence and degradability Elimination rate Method of analysis Method Validation Biological degradability not applicable 12.3. Bioaccumulative potential The product has not been tested. Because of the product's consistency and low solubility in water bioavailability is not likely. 12.4. Mobility in soil not applicable 12.5. Results of PBT and vPvB assessment The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII. 12.6. Other adverse effects General regulation No adverse ecological effects are known or expected to be a concern under normal use. Do not allow uncontrolled leakage of product into the environment. The ecotoxic effect of the product has not been tested. The information on this was derived from products of similar structure or composition. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste code No. Name of waste 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous substances Wastes marked with an asterisk are considered to be hazardous waste pursuant to Directive 2008/98/EC on hazardous waste. Recommendations for the product Remove in accordance with local official regulations. Recommendations for packaging Carefully polymerize content with water or alkali. Dispose of according to the local waste regulations. General information Assignment to a waste code number / waste identification according to the EWC is to be carried out on a sector or process-specific basis. Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed 19.06.2015 revision 18.06.2015 (GB) Version 8.4 Contact VA 100 WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 9/9 SECTION 14: Transport information ADR/RID IMDG IATA-DGR 14.1. UN number -- - 14.2. UN proper shipping name -- - 14.3. Transport hazard class(es) -- - 14.4. Packing group -- - 14.5. Environmental hazards -- - 14.6. Special precautions for user No information available. 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code not applicable Transport/further information No dangerous goods as defined by the transport regulations - ADR/RID, IMDG, ICAO/IATA-DGR. ! SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture ! VOC standard VOC content 2 % VOC value 21,2 g/L 15.2. Chemical Safety Assessment Chemical safety assessments for substances in this mixture were not carried out. SECTION 16: Other information Recommended uses and restrictions National and local regulations concerning chemicals shall be observed. For industrial use only. Further information Each user is responsible for the implementation of the national special regulations. The information contained herein is based on the state of our knowledge. It characterizes the product with regard to the appropriate safety precautions. It does not represent a guarantee of the properties of the product. Please observe the following disclaimer! --- Our safety data sheets have been compiled according to effective EUdirectives, WITHOUT taking into account the special national directives concerning the handling of hazardous substances. Indication of changes: "!" = Data changed compared with the previous version. Previous version: 8.3 H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation.